| Province | ZIP (from ... to) | Population | Municipalities |
|---|---|---|---|
| Arezzo | 52010 ... 52100 | 333,240 | 36 |
| Florence | 50012 ... 50068 50121 ... 50145 (CAP Florence) | 988,068 | 41 |
| Grosseto | 58010 ... 58100 | 215,005 | 28 |
| Livorno | 57014 ... 57038 57121 ... 57128 (CAP Livorno) | 325,749 | 19 |
| Lucca | 55011 ... 55100 | 381,390 | 33 |
| Massa-Carrara | 54010 ... 54100 | 186,783 | 17 |
| Pisa | 56010 ... 56048 56121 ... 56128 (CAP Pisa) | 418,439 | 37 |
| Pistoia | 51010 ... 51100 | 289,925 | 20 |
| Prato | 59013 ... 59100 | 259,657 | 7 |
| Siena | 53011 ... 53100 | 259,460 | 35 |